A Kinetic and Mechanistic study of the Effect of the Substituent on the Rate of Reduction of PX-ArTeCl3
Abstract
Abstract
The effect of the substituent on the rate of reduction of PX-ArTeCl3 (X=H, OH, OCH3, OC2¬H¬5) has been investigated kinetically. The reduction obeys a second order rate law and hammett equation, it is a first order in each of the oxidizing and reducing agents. The rate and δP Values of the reaction have been determined. It is found that the rate of reduction increases in the order, H<
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